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Relaxations of Excited States and Photo-Induced Structural Phase Transitions are the topics discussed during the 19th Taniguchi Symposium. Here, 27 worldwide renowned physicists and chemists report recent topics related to this quite new theme from the view points of both material science and solid-state spectroscopy. The phenomena within the scope of this conference are as follows: >Neural-ionic transistions of organic charge-transfer salts. >Optical excitations, lattice relaxactions and photo-induced phenomena. >Optical properties of the C60 crystal and photo-induced polymerization. >Self-trapped excitons, polarons, solitons and other nonlinear photo-excitations in various insulators. >Photo-induced structural changes in ferroelectrics, semiconductors and amorphous materials.
|Statement||edited by Keiichiro Nasu|
|Series||Springer Series in Solid-State Sciences -- 124, Springer series in solid-state sciences -- 124.|
|LC Classifications||QC350-467, TA1501-1820, QC392-449.5, TA1750-1750.22|
|The Physical Object|
|Format||[electronic resource] :|
|Pagination||1 online resource (xii, 277p. 135 illus.)|
|Number of Pages||277|
|ISBN 10||364264516X, 3642607020|
|ISBN 10||9783642645167, 9783642607028|
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About this book Relaxations of Excited States and Photo-Induced Structural Phase Transitions are the topics discussed during the 19th Taniguchi Symposium. Here, 27 worldwide renowned physicists and chemists report recent topics related to this quite new theme from the view points of both material science and solid-state spectroscopy.
A new class of insulating solids was recently discovered. When irradiated by a few visible photons, these solids give rise to a macroscopic excited domain that has new structural and electronic orders quite different from the starting ground : Hardcover.
Ogawa T., Nagaosa N. () Mean-Field Theory of Photo-Induced Structural Phase Transitions. In: Nasu K. (eds) Relaxations of Excited States and Photo-Induced Structural Phase Transitions. Springer Series in Solid-State Sciences, vol Cited by: 2.
An electron in an isulating solid induces a local lattice distortion around itself,when it is excited by a photon.
This phenomenon called “lattice relaxation” of an optical excitation has been Multistabilities of the Ground States, Proliferations of Excitons and Photo-Induced Structural Phase Transitions | Cited by: 2.
A general concept for photoinduced structural phase transitions is developed, in terms of the hidden multi-stability of the ground state and the proliferations of optically excited by: We apply this view-point to the latter system to interrelate the photo-induced phase transition and the phase transition under thermal equilibrium, with the use of a microscopic model with dipole-dipole interaction between the parity-broken self-trapped by: 5.
Relaxations of Excited States and Photo-Induced Structural Phase Transitions are the topics discussed during the 19th Taniguchi Symposium. Here, 27 worldwide renowned physicists and chemists. Photoinduced Phase Transitions in One-Dimensional Correlated Electron Systems (H Okamoto et al.) Probing Photoinduced Structural Phase Transitions by Fast or Ultra-Fast Time-Resolved X-Ray Diffraction (H Cailleau et al.) Readership: Graduate students and researchers in solid state optics, nonlinear science, chaos and dynamical systems.
Domain-wall Dynamics of the photo-induced phase transition in polydiacetylene (PDA) single crystals has been investigated by time-resolved spectroscopy. It was found that primary process of the photo-induced phase transition is mostly completed within 50 : S.
Koshihara, K. Akimoto, Y. Tokura, K. Takeda, T. Koda. Photoinduced phase transitions these solids give rise to a macroscopic excited domain that has new structural and electronic orders quite different from the starting ground state.
This occurrence is called "photoinduced phase transition", and this multi-authored book reviews recent theoretical and experimental studies of this new phenomenon.
Photo-induced phase transitions in spin-crossover complex [Fe(II)(2-pic) 3]Cl 2 EtOH were investigated by X-ray absorption spectroscopy (XAS) technique. In situ XAS results showed that the metal-ligand (Fe–N) bond distance expands by ca.
Å upon photo-induced (S=0→S=2) spin find that nearly octahedral (O h) symmetry of FeN 6 coordination remains in the photo-induced high Cited by: In: Relaxations of Excited States and Photo-Induced Structural Phase Transitions, Nasu, K.
(Ed.), Springer-Verlag, Berlin, p. Downloaded by [Stony Brook University] at 27 October Photo-induced magnetic transitions show nonlinear characteristics such as threshold light intensity, incubation period and phase separation .
Photo-induced phase transitions are often discussed in terms of trapping of metastable spin state, i.e., light-induced excited spin state trapping Cited by: This is nothing but the photoinduced structural-phase transition.
We can think of a simple and intuitive scenario for this transition in such a way as is schematically shown in Fig.
That is, a single photon can make a single neutral pair, and after that, Author: Keiichiro Nasu, Hideo Mizouchi, Huai Ping. (a) The phase transition can start when the atom is not only in the excited state but also in the ground state.
In the case of strong interaction between atoms (large value of k), the process of phase transition may begin only when the atom is in the excited by: 7. Theories of photoinduced phase transitions have developed along with the progress in experimental studies, especially concerning their nonlinear characters and transition dynamics.
At an early stage, paths from photoinduced local structural distortions to global ones are explained in Cited by: Relaxation of optical excitations, hidden multi-stability and photo-induced phase transitions As is already well-known, an electron in an insulating crystal induces a local lattice distortion around itself when excited by a photon.
Get this from a library. Relaxations of excited states and photo-induced structural phase transitions: proceedings of the 19th Taniguchi Symposium, Kashikojima, Japan, July[K Nasu;]. 5 E. Hanamura, in Relaxations of Excited States and Photo-Induced Structural Phase Tr ansitions (Springer Berlin Heidelberg, Berlin, Heidelberg, ) pp.
34– Itinerant type quantum many-body theories for photo-induced structural phase transitions (PSPTs) are reviewed in close connection with various recent experimental results related to this new optical phenomenon.
There are two key concepts: the hidden multi-stability of the ground state, and the proliferations of optically excited by: The phase transition is caused by a metal-to-metal charge transfer from Mn II to Fe III and a Jahn–Teller distortion of the produced Mn III ion.
At the ferromagnetic state in LT phase of 2, the photo-induced phase transition is observed, i.e., magnetization is quenched by the irradiation with only one shot of laser pulse. This phenomenon is Cited by: 2. The Classical Approach to Structural Phase Transitions Antiferrodistortive Transitions The classical theory of phase transitions is built upon the Landau theory of expanding the free energy in a power series9 developed in A simplified form of this theory can be obtained if the displacement occurring at a phase transition has three.
An attempt to make a movie of wave-packet motion is mentioned. In Sec. 1, a brief introduction to the dynamics of the excited states in quasi-one-dimensional platinum complexes is given.
It is stressed that this system can be a good model system for investigating the photo-induced structural phase : Tohru Suemoto, Shinichi Tomimoto, Taira Matsuoka. ISBN: OCLC Number: Description: viii, pages: illustrations ; 24 cm: Contents: Theories for photoinduced structural phase transitions and their dynamics / Keiichiro Nasu --Time-resolved spectroscopy of the dynamics of photoinduced ionic-to-neutral phase transition in tetrathiafulvalen-p-chloranil crystals / Katsumi Tanimura --Study on the cooperative.
Nasu, Ed., Relaxations of Excited States and Photo-Induced Structural Phase Transitions, vol. of Springer Series in Solid- State Sciences, Springer, Berlin, Germany, Magnetic.
Relaxations of Excited States and Photo-Induced Structural Phase Transitions: Proceedings of the 19th Taniguchi Symposium, Kashikojima, Japan, July 18–23, Book Jan 2 Relaxations of Excited States and Photo-induced Structural Phase Transitions, ed.
(Springer-Verlag, Berlin, ). Crossref, Cited by: 5. We review recent progress of theoretical studies for the photoinduced phase tran- sitions (PIPTs) to clarify what the PIPTs are. There are two types of the PIPTs: (a) global change via optically excited states and (b) new material phase creation in optically excited states.
First, concerning (a), photoinduced structural phase transitions via excited electronic states are discussed using a Author: Tetsuo Ogawa. Journal of Nanomaterials / / Article. Article Sections. Photoinduced phenomena including phase transition and surface photoactivation are becoming a hot topic in the light-matter interaction domain and are of a specific Relaxations of Excited States and Photo-Induced Structural Phase Transitions, vol.
of Springer Series in Cited by: 3. Books. Publishing Support. Login. Nasu K Relaxations of Excited States and Photo-Induced Structural Phase Transitions (Berlin: Springer) Crossref Google Scholar  Nasu K Photoinduced Phase Transitions (Singapore: World Scientific) Crossref Google Scholar Cited by: 3.
Acta Cryst. A54, Structural phase transition nomenclature Report of an IUCr Working Group on phase transition nomenclature.
J.-C. TOLÉDANO, a A. GLAZER, b TH. HAHN, c E. PARTHÉ, d,e R. ROTH, f R. BERRY, g § R. METSELAAR h AND S. ABRAHAMS i * a Laboratoire des Solides Irradiés, Ecole Polytechnique, F Palaiseau CEDEX, France, b.
Phospholipid phase transitions: kinetics and structural mechanisms. Chemistry and Physics of Lipids57 (), DOI: /(91)J. Tenchov. On the reversibility of the phase transitions in lipid-water by: One-shot-laser-pulse-induced demagnetization in rubidium manganese hexacyanoferrate Infrared spectra before and after the irradiation indicated that this photomagnetic effect was caused by a photoinduced phase transition from the Fe(II)–CN–Mn(III) phase Relaxations of Excited States and Photo-Induced Structural Phase TransitionsCited by: Various photoinduced phase transitions have been reported in transition metal oxides such as Pr (Ca 1 − y Sr y) MnO 3 and in diluted magnetic semiconductors including In 1 − x Mn x As.
In Pr (Ca 1 − y Sr y) MnO 3, the optically excited electrons locally destroy the spin-charge-orbital ordering, followed by rapid Cited by: 2. © The Physical Society of Japan. KEYWORDS: photo-induced phase transition, photo-induced phase, rapidly-cooled phase, prussian blue analog.
References. 1 i and oto: J. Photochem. Photobiol. 12 :Relaxations of Excited States and Photo-Induced Structual Phase Transitions Cited by: 4. For the photoinduced ionic→neutral phase transition in the organic charge transfer crystal TTF-CA, we, at first, theoretically propose an adiabatic path of this transition, which starts from a single charge transfer exciton in ionic phase, but finally reaches a neutral domain with a macroscopic size.
In the next, using a more simplified model, we theoretically study the nonequilibrium. Following the initial ultrafast photo-induced structural phase transit20,21,22,23, the optical excitation creates an unstable high-energy monoclinic (M) state, where the energy supplying the latent heat has already been stored in the system before the transition by: While d-d transitions are in principle forbidden by symmetry, they become weakly-allowed in a crystal when the symmetry is broken by structural relaxations or other effects.
Absorption of a photon resonant with a d - d transition leads to the creation of an electron-hole pair on a single atomic site, which can be treated as a Frenkel exciton.
We report on the photomagnetic effect in RbMn[Fe(CN)6]⋅H2O ferromagnet. Magnetization of this system was reduced by irradiation with only one-shot of laser pulse ( nm) at 3 K. This photodemagnetization was observed only when the laser power density (P) was above mJ cm−2 pulse−1. The quantum yield was above one and reached at P=43 mJ cm−2 pulse−1, showing that Cited by: photo-induced HS state after LIESST (Light-Induced Excited Spin State Trapping) effect .
For so doing, two situations are investigated: (i) the perfect rectangular lattice; and (ii) and a lattice with a structural defect, which is simply modeled by a hole located in the center. The paper is organizedCited by: 2. Shelby GT Barn Find and Appraisal That Buyer Uses To Pay Widow - Price Revealed - Duration: Jerry Heasley Recommended for you.
This article describes a temperature- and photo-induced phase transition in rubidium manganese hexacyanoferrate, RbMn(Fe(CN) 6).
This compound displays a drop in the magnetic susceptibility at K (= T 1/2↓) and an abrupt increase in the magnetic susceptibility at K (= T 1/2↑) in the cooling and warming processes, respectively. This phase transition is accompanied by a structural.Within the configuration coordinate model, photo-induced lattice relaxation and chemical reaction are described equally to both ground and relaxed excited states, to provide a novel and global perspective on structural phase transitions and the nature of interatomic bonds.